680
GC CHROMATOGRAMS |
FORENSIC/PHARMACEUTICAL
Basic Drugs
7
Column:
Rtx
®
-200, 30m, 0.25mm ID, 0.25µm (cat.# 15023)
Sample:
1.0µL split injection of a basic drug sample (1mg/mL)
Conc.:
1,000ng/µL
Oven temp.:
100°C to 325°C @ 4°C/min. (hold 10 min.)
Inj./det. temp.:
250°C/320°C
Carrier gas:
helium
Linear velocity:
30cm/sec. set @ 100°C
FID sensitivity:
1.28 x 10
-10
AFS
Split ratio:
50:1
1
2
4
6
8
10
11
3,5
14
19
17
18
22
23
21
20,25
24
30
28,29
27
37
34
33
36 38
35
31,32
26
16
15
13
12
9
min.
10
20
30
40
50
60
GC_PH00237
Basic Drugs (Underivatized)
Rtx®-200
1. nicotine
2. benzocaine
3. cotinine
4. meperidine
5. caffeine
6. benzphetamine
7. ketamine
8. diphenhydramine
9. lidocaine
10. phenyltoloxamine
11. tripelennamine
12. phenothiazine
13. dextromethorphan
14. methadone
15. amitriptyline
16. trimipramine
17. tetracaine
18. pyrilamine
19. medazepam
20. bupivacaine
21. scopolamine
22. codeine
23. morphine
24. diazepam
25. chlorpromazine
26. temazepam
27. flunitrazepam
28. bromazepam
29. prazepam
30. acetopromazine
31. flurazepam
32. papaverine
33. clonazepam
34. haloperidol
35. alprazolam
36. triazolam
37. thioridazine
38. trazodone
Basic Drugs (Underivatized)
Rxi®-5ms
Column:
Rxi
®
-5ms, 30m, 0.25mm ID, 0.25µm (cat.# 13423)
Sample:
1,000µg/mL each in methanol
Inj.:
1.0µL split (50:1), 20ng each compound on column; Siltek
®
treated
4mm gooseneck splitless inlet liner (cat.# 20799-214.5)
Inj. temp.:
250°C
Carrier gas:
helium
Linear velocity: 30cm/sec., constant pressure
Oven temp.:
100°C to 220°C @ 15°C/min., to 330°C @ 10°C/min. (hold 5 min.)
Det.:
Agilent 5973 MSD
Transfer line
temp.:
300°C
Scan range:
35-550
Tune:
PFTBA
Ionization:
EI
1. amphetamine
2. methamphetamine
3. nicotine
4. cotinine
5. caffeine
6. benzphetamine
7. ketamine
8. phencyclidine
9. methadone
10. cocaine
11. codeine
12. scopolamine
13. alprazolam
GC_PH00814
Rxi® Technology!
Exceptionally inert,
ultra low- bleed
capillary columns.
Website :
E-mail :
TelNo : 03 9762 2034 . . . in AUSTRALIA
Mar 2011
