Figure 3
Restek Corporation • (800) 356-1688 • (814) 353-1300 •
Rtx
®
-5SilMS, 30m, 0.25mm ID, 0.25µm (cat.# 12723)
Sample:
16µg/mL inmethylene chloride
Inj.:
1µLsplitless (hold 0.4min.),
DrilledUniliner
®
liner (cat.# 21054)
Inj. temp.:
300°C
Carrier gas:
1mL/min., constant flow
Linear velocity:
34cm/sec.
Oven temp.:
35°C (hold 2min.) to 260°C@ 20°C/min., to
330°C@ 6°C/min. (hold 1min.)
Det.:
MS
Transfer line temp.: 280°C
Scan range:
35–550amu
Ionization:
EI
Mode:
full scan
phenol (m/z 94)
aniline (m/z 93)
bis(2-chloroethyl)ether (m/z 93)
GC_EV00562
1,3-dichlorobenzene (m/z 146)
1,4-dichlorobenzene (m/z 146)
1,2-dichlorobenzene (m/z 146)
GC_EV00563
benzo(b)fluoranthene (m/z 252)
benzo(k)fluoranthene (m/z 252)
GC_EV00564
indeno(1,2,3-cd)pyrene (m/z 276)
dibenzo(a,h)antracene (m/z 278)
GC_EV00565
Extracted ion chromatograms show resolution of closely-eluting compounds.
Peak List for Figure 2
1.N-nitrosodimethylamine
2.pyridine
3.methyl methanesulfonate
4.2-fluorophenol
5. ethyl methanesulfonate
6.phenol-d6
7.phenol
8. aniline
9.bis(2-chloroethyl)ether
10.2-chlorophenol
11.1,3-dichlorobenzene
12.1,4-dichlorobenzene-d4
13.1,4-dichlorobenzene
14.1,2-dichlorobenzene
15.benzyl alcohol
16.2-methylphenol
17.bis(2-chloroisopropyl)ether
18. acetophenone
19.4-methylphenol/3-methylphenol
20.N-nitroso-di-
n
-propylamine
21.hexachloroethane
22.nitrobenzene-d5
23.nitrobenzene
24. isophorone
25.2-nitrophenol
26.2,4-dimethylphenol
27.bis(2-chloroethoxy)methane
28.benzoic acid
29.2,4-dichlorophenol
30.1,2,4-trichlorobenzene
31.naphthalene-d8
32.naphthalene
33.2,6-dichlorophenol
34.4-chloroaniline
35.hexachloropropene
36.hexachlorobutadiene
37.4-chloro-3-methylphenol
38. isosafrole
39.2-methylnaphthalene
40.1-methylnaphthalene
41.hexachlorocyclopentadiene
42.1,2,4,5-tetrachlorobenzene
43.2,4,6-trichlorophenol
44.2,4,5-trichlorophenol
45.2-fluorobiphenyl
46. safrole
47.2-chloronaphthalene
48.2-nitroaniline
49.1,4-naphthoquinone
50.dimethylphthalate
51.1,3-dinitrobenzene
52.2,6-dinitrotoluene
53. acenaphthylene
54. acenaphthene-d10
55.3-nitroaniline
56. acenaphthene
57.2,4-dinitrophenol
58.pentachlorobenzene
59.4-nitrophenol
60.dibenzofuran
61.2,4-dinitrotoluene
62.2,3,4,6-tetrachlorophenol
63.diethyl phthalate
64. fluorene
65.4-chlorophenyl phenyl ether
66.4-nitroaniline
67.4,6-dinitro-2-methylphenol
68.diphenylamine
69. azobenzene
70.2,4,6-tribromophenol
71.phenacetin
72.4-bromophenyl phenyl ether
73.hexachlorobenzene
74.pentachlorophenol
75.pentachloronitrobenzene
76.phenanthrene-d10
77.dinoseb
78.phenanthrene
79. anthracene
80.di-
n
-butylphthalate
81.4-nitroquinoline-1-oxide
82. isodrin
83. fluoranthene
84.benzidine
85.pyrene
86.
p
-terphenyl-d14
87. aramite
88. chlorbenzilate
89.kepone
90.butyl benzyl phthalate
91.benzo(a)anthracene
92.3,3'-dichlorobenzidine
93. chrysene-d12
94. chrysene
95.bis(2-ethylhexyl)phthalate
96.di-
n
-octyl phthalate
97.benzo(b)fluoranthene
98.benzo(k)fluoranthene
99.benzo(a)pyrene
100.perylene-d12
101.3-methylcholanthrene
102. indeno(1,2,3-cd)pyrene
103.dibenzo(a,h)anthracene
104.benzo(ghi)perylene
7
8
9
11
13
14
97
98
102
103
