DEl
innovationsinchemical detection
Ethanol
in
Gasoline
(6890 Ge)
FlO
2mln.
BISPHENOL A. (SPA.)
FlO
1024 pA f'ull scale
Ph_ne>1
SPA
1
TI0-1 -Ni'tr<:>gen
5"12 pA flLlll scoal_
- Ethanol
oxygenate selective
TID-1 detector
(nitrogen carrier
&
detector gas)
Ph_ne>1
29_ng
SPA
2.7 ng
Oxygenate selective TIO-1 ionization provides easy
analysis of Ethanol amidst many Hydrocarbons of
Gasoline using a single Nitrogen supply for both GC
carrier and detector gas.
AglI_nt 6890GC
Oxygenate selective TIO·1 provides SPA detectivity
which is 50times better than an FlO.TIO·1 response to
Phenols, Carboxylic Acids, Glycols, Salicylates, and
Vanillin is especially large compared to other classesof
Oxygenates.
peCE (18ng each) and PAH (92ng each)
FlO
512 pA full scale
FIDdetects
PAH,
but only
minimal PBDE signals
.1<:+-.-+--
PAH-->
M
B
T
FlO
SpA
"full scale
1
I
~
column bleed
4
tetra BDE
TID-3-Nitrogen
32 pA f.s.
TID-3 detects PBDEwith good
selectivity versus PAH
heptaBDE
deca BDE
TI0-3-N2
SpA
"full scale
M
1
2
3
LikeTID·1,TID-3ionization requiresonlyNitrogenasthe
detectorgas, althoughTID·3 is designed to operateat a
higher temperature to eliminate peak tailing.
Water Solution: M=2500ngMethanol, B=47ngBenzene,
T=47ngToluene;
Tnhalornethanes, O.64ng each
1=CHCI
3 •
2=CHCI
2Br.
3=CHCIBr
2 •
4=CHBr
3
