RtxPresentations07 - page 954-955

Rtx-1
OVImethods allow forGC/MSconfirmational analysis
to identify complex chromatograms. GC/MS
compound identification errors are common since
ketones& acetates share parent ions (43). Alkanes&
alkenes also present challenges since these
compounds contain the 57 ion. The chromatogram
shown illustrates the problemswithnon-polar phase
with this compound list. Polar compound such as
ethylene glycol have poor solubility in the dimethyl-
polysiloxane phase resulting in poor sensitivity&
linearity. The alcohols are retained less relative to the
non-polar analytes.
1...,934-935,936-937,938-939,940-941,942-943,944-945,946-947,948-949,950-951,952-953 956,958-959,960-961,962,964-965,966-967,968,970-971,972-973,974-975,...
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