93. 1,3,5-trinitrobenzene
94. phenacetin
95. 4-bromophenyl phenyl ether
96. hexachlorobenzene
97. atrazine
98. 4-aminobiphenyl
99. pentachlorophenol
100. pentachloronitrobenzene
101. propyzamide
102. phenanthrene
103. anthracene
104. carbazole
105. di-
n
-butylphthalate
106. 4-nitroquinoline-1-oxide
107. methapyriline
108. isodrin
109. fluoranthene
110. benzidine
111. pyrene
112. Aramite (isomer)
113.
p
-terphenyl-d14 (SS)
114. Aramite (isomer)
115. dimethylaminoazobenzene
116. dichlorobenzilate
117. 3,3
'
-dimethylbenzidine
118. benzyl butyl phthalate
119. Kepone
120. bis(2-ethylhexyl)adipate
121. 2-acetylaminofluorene
122. 3,3
'
-dichlorobenzidine
123. chrysene
124. benzo(a)anthracene
125. bis(2-ethylhexyl)phthalate
126. di-
n
-octyl phthalate
127. benzo(b)fluoranthene
128. 7,12-dimethylbenzo(a)anthracene
129. benzo(k)fluoranthene
130. benzo(a)pyrene
131. 3-methylcholanthrene
132. dibenzo(a,j)acridine
133. indeno(1,2,3-cd)pyrene
134. dibenzo(a,h)anthracene
135. benzo(ghi)perylene
566
GC CHROMATOGRAMS |
ENVIRONMENTAL
Semivolat i les
Semivolatile Organics
US EPA Method 8270-Appendix IX
Rxi®-5Sil MS
1. 1,4-dioxane
2. N-nitrosodimethylamine
3. pyridine
4. ethyl methacrylate
5. 2-picoline
6. N-nitrosomethylethylamine
7. methyl methanesulfonate
8. 2-fluorophenol
9. N-nitrosodiethylamine
10. ethyl methanesulfonate
11. benzaldehyde
12. phenol
13. aniline
14. bis(2-chloroethyl)ether
15. pentachloroethane
16. 2-chlorophenol
17. 1,3-dichlorobenzene
18. 1,4-dichlorobenzene
19. benzyl alcohol
20. 1,2-dichlorobenzene
21. 2-methylphenol
22. bis(2-chloroisopropyl)ether
23. 4-methylphenol
Column:
Rxi
®
-5Sil MS, 30m, 0.25mm ID,
0.25µm, w/10m Integra-Guard™
(cat.# 13623-127)
Sample:
8270 MegaMix
®
(cat.# 31850),
Appendix IX Mix #1 (cat.# 31625),
Appendix IX Mix #2 (cat.# 31806),
Revised B/N Surrogate Mix (cat.# 31887),
Acid Surrogate Mix (4/89 SOW) (cat.# 31025),
8270 Benzidines Mix (cat.# 31852)
in methylene chloride, 10ng on-column
Inj.:
1.0µL pulsed splitless, pulse 20psi @ 0.3 min.,
60mL/min. @ 0.25 min. 4mm single gooseneck
inlet liner w/wool (cat.# 22405)
Inj. temp.: 275°C
Carrier gas: helium, constant flow
Flow rate: 1.2mL/min.
Oven temp.: 50°C (hold 0.5 min.) to 260°C @ 20°C/min. to
280°C @ 5°C/min. to 340°C (hold 2 min.) @
18°C/min.
Det:
MS
Transfer
line temp.: 280°C
Scan range: 35-550
Ionization: EI
Mode:
scan
24. 3-methylphenol
25. acetophenone
26. N-nitroso-di-
n
-propylamine
27. nitrosopyrrolydine
28. 4-nitrosomorpholine
29.
o
-toluidine
30. hexachloroethane
31. nitrobenzene-d5 (SS)
32. nitrobenzene
33. N-nitrosopiperidine
34. isophorone
35. 2-nitrophenol
36. 2,4-dimethylphenol
37. bis(2-chloroethoxy)methane
38. 2,4-dichlorophenol
39.
α,α
-dimethylphenylamine
40. 1,2,4-trichlorobenzene
41. naphthalene
42. 2,6-dichlorophenol
43. 4-chloroaniline
44. hexachloropropene
45. hexachlorobutadiene
46. N-nitroso-
n
-butylamine
47. caprolactam
48. 1,4-phenylenediamine
49. 4-chloro-3-methylphenol
50. isosafrole
51. 2-methylnaphthalene
52. 1-methylnaphthalene
53. hexachlorocyclopentadiene
54. 1,2,4,5-tetrachlorobenzene
55. isosafrole
56. 2,4,6-trichlorophenol
57. 2,4,5-trichlorophenol
58. 2-fluorobiphenyl (SS)
59. safrole
60. biphenyl
61. 2-chloronaphthalene
62. 1-chloronaphthalene
63. diphenyl ether
64. 2-nitroaniline
65. 1,4-naphthoquinone
66. 1,4-dinitrobenzene
67. dimethylphthalate
68. 1,3-dinitrobenzene
69. 2,6-dinitrotoluene
70. acenaphthylene
71. 1,2-dinitrobenzene
72. 3-nitroaniline
73. acenaphthene
74. 2,4-dinitrophenol
75. 4-nitrophenol
76. pentachlorobenzene
77. dibenzofuran
78. 2,4-dinitrotoluene
79. 1-naphthalamine
80. 2,3,4,6-tetrachlorophenol
81. 2,3,5,6-tetrachlorophenol
82. 2-naphthylamine
83. diethyl phthalate
84. fluorene
85. 4-chlorophenyl phenyl ether
86. 2-methyl-5-nitroaniline
87. 4-nitroaniline
88. 4,6-dinitro-2-methylphenol
89. diphenylamine
90. azobenzene
91. 2,4,6-tribromophenol (SS)
92. diallate
GC_EV01077
Rxi® Technology!
Exceptionally inert,
ultra low- bleed
capillary columns.
• Single gooseneck liner w/wool
• 10ng on-column
• Silarylene phase
• 0.25mm ID, 10m Integra-Guard®
Website :
E-mail :
TelNo : 03 9762 2034 . . . in AUSTRALIA
Mar 2011
