559
GC CHROMATOGRAMS |
ENVIRONMENTAL
Semivolat i les
Polycyclic Aromatic Hydrocarbons
US EPA Method 610
Rxi®-5ms
1. naphthalene
2. acenaphthylene
3. acenaphthene
4. fluorene
5. phenanthrene
6. anthracene
7. fluoranthene
8. pyrene
9. benzo(a)anthracene
10. chrysene
11. benzo(b)fluoranthene
12. benzo(k)fluoranthene
13. benzo(a)pyrene
14. indeno(1,2,3-cd)pyrene
15. dibenzo(a,h)anthracene
16. benzo(ghi)perylene
GC_EV00824
Column:
Rxi
®
-5ms, 30m, 0.25mm ID, 0.25µm
(cat.# 13423)
Sample:
SV Calibration Mix #5/610 PAH Mix
(cat.# 31011)
Inj.:
1.0µL, 10ppm each analyte (10ng on
column), splitless (hold 0.1 min.)
4mm Drilled Uniliner
®
inlet liner
(hole near bottom) (cat.# 20771)
Instrument:
Agilent 6890
Inj. temp.:
275°C
Carrier gas:
helium, constant flow
Flow rate:
1.2mL/min.
Oven temp.:
75°C (hold 0.5 min.) to 245°C @ 25°C/min.,
to 330°C @ 4°C/min. (hold 1 min.)
Det.:
Agilent 5973 GC/MS
Transfer line
temp.:
280°C
Scan range:
35-550amu
Solvent delay:
2 min.
Tune:
DFTPP
Ionization:
EI
14.75 15.00 15.25 15.50 15.75
benzo(b)fluoranthene benzo(k)fluoranthene
Polycyclic Aromatic Hydrocarbons
US EPA Method 610
(with Internal Standards & Surrogates)
Rxi®-5ms
GC_EV00825
1. 2-fluorophenol
2. phenol-d6
3. 1,4-dichlorobenzene-d4
4. nitrobenzene-d5
5. naphthalene-d8
6. naphthalene
7. 2-fluorobiphenyl
8. acenaphthylene
9. acenaphthene-d10
10. acenaphthene
11. fluorene
12. 2,4,6-tribromophenol
13. phenanthrene-d10
14. phenanthrene
15. anthracene
16. fluoranthene
17. pyrene
18.
p
-terphenyl-d14
19. benzo(a)anthracene
20. chrysene-d12
21. chrysene
22. benzo(b)fluoranthene
23. benzo(k)fluoranthene
24. benzo(a)pyrene
25. perylene-d12
26. indeno(1,2,3-cd)pyrene
27. dibenzo(a,h)anthracene
28. benzo(ghi)perylene
Column:
Rxi
®
-5ms, 30m, 0.25mm ID, 0.25µm (cat.# 13423)
Sample:
SV Calibration Mix #5/610 PAH Mix
(cat.# 31011), Acid Surrogate Mix (4/89 SOW)
(cat.# 31025), B/N Surrogate Mix (4/89 SOW)
(cat.# 31024), SV Internal Standard Mix
(cat.# 31206)
Inj.:
1.0µL, 10ppm each analyte (10ng on
column; 40ng each internal standard),
splitless (hold 0.1 min.)
4mm Drilled Uniliner
®
inlet liner
(hole near bottom) (cat.# 20771)
Instrument: Agilent 6890
Inj. temp.:
275°C
Carrier gas: helium, constant flow
Flow rate:
1.2mL/min.
Oven temp.: 75°C (hold 0.5 min.) to 245°C @ 25°C/min.,
to 330°C @ 4°C/min. (hold 1 min.)
Det.:
Agilent 5973 GC/MS
Transfer line
temp.:
280°C
Scan range: 35-550amu
Solvent delay:2 min.
Tune:
DFTPP
Ionization: EI
Rxi® Technology!
Exceptionally inert,
ultra low- bleed
capillary columns.
Rxi® Technology!
Exceptionally inert,
ultra low- bleed
capillary columns.
Website :
E-mail :
TelNo : 03 9762 2034 . . . in AUSTRALIA
Mar 2011
