PCDDs
&
PCDFs Isomers
~TM
0
5-MS
,
ultra-Iovv bleeding column
/
/
Oeta-
S
Tetra-
Penta-
Hexa-
Hepta-
&
5: VOltageSIR16Channels EI+
1°~1
35.54,443.7399
~
1.74e7
I
,
,
1,'00
I
,
,
r oo
,
,
,
,
,
14.00
16.00
20.00
22.00
26.00
28.00
30.00
32.00
34.00
36.00
RT-070212-10
5:Voltage SIR16ChannelsEI+
1 °~1
3532, 459.7348
Column:
MEGA-5 MS
Xll
-
0.15mm, 0.1OlJm, 30m
~
145e7
,
,
roo
1
,
,
I
~'oo
,
,
,
,
I
,
CatalogCode:MS-5XIL-015-0I0-30
14.00
1600
20 00
22.00
26.00
28.00
30.00
32.00
34.00
36.00
RT-070212-10
4:Voltage SIR 13ChannelsEI+
1 °~l
2918
3224
407.7818
Retention Gap:
DPTMDSO.25mm, 2.5m
A
J
2.41e7
,
I
1,'00
1
I
,
II
,"C"
j
,
I
I
,
CatalogCode:RETG-DPTMDS-025-2-5
14.00
16.00
20.00
22.00
26.00
28.00
30.00
32.00
34.00
36.00
RT-070212-10
4:Voltage SIR13Channels EI+
30.30
31.51
423.7766
Connector:
Press-Fit Union
1°~l
~
~
1.83e7
,
i
roo
1
I
,
'r"
j
,
,
I
I
I
CatalogCode:PFITUN-O15-025-1
14.00
16.00
20.00
22.00
26.00
28.00
30 00
32.00
3400
36 00
RT-070212-10
3: VOltage SIR 15Channels EI+
1 °~l
24t
2619~27.25
389.8157
'"
2.11e7
Conditions
0
14.00
1600
1
8 00
2000
22.00
24.00
26.00
28.00
30.00
32.00
34.00
36.00
RT-070212-10
3:Voltage SIR 15ChannelsEI+
OvenProgram: 160°C,10oOmin, 190°C,2.so0min,
255°C,
1 °~l
~h68
25.47256126.5927.78
3738208
4°0min, 310°C.
'"
M
(ri
3.30e7
0
CarrierGas: Heliumpressure programmed from
14.00
16.00
[ 8 00
20.00
22.00
1
24
.
00
26.00
28.00
30.00
32.00
34.00
36.00
RT-070212-10
2: Voltage SIR 14 Channels EI+
400kPa to 526kPa
@
3kPaimin.
19~58
22.17,22.60
355.8546
Injector:direct deactivated glass liner, heated
@
260°C.
1 °~l
21.26
1A
2.1ge7
0
14.00
16.00
[ 8 00
20.00
22.00 1124.00
26.00
28.00
30 00
32 00
34.00
36.00
Sample
RT-070212-10
2: VOltage SIR14 Channels EI+
1 °~l
20t
W
9
22
h
9
i
339.8597
'"
19 49
342e7
Forallthe chromatograms shownhere,WellingtonLaboratories
0
14.00
1600
~ 8 00
20.00
22.00
11
24 00
26.00
28.00
30.00
32.00
34.00
36.00
capillary columnperformance testmixture (WellingtonLabs.
RT-070212-10
1: Voltage SIR17ChannelsEI+
catalog code:TDTFWD) wasusedexceptwherespecified
1 0~~
~8r
339.8597
(seeslide10, 12and 14).
'"
46ge7
0
14.00
16.00
~
8.00
20.00
22.00
11
24 00
26.00
28.00
30.00
32.00
34.00
36.00
RT-070212-10
1: Voltage SIR 17Channels EI+
Legend
14.89 16.47 17.12 18.04
3218936
1 °~l
!~
A/
A&
~
3.82e7
,
"'00 ' 1' 00
I
I
,
r
j
,
,
I
j
j
Furans isomers (PCDFs)
14.00
20.00
22.00
26.00
28 00
30 00
32.00
34.00
36.00
RT-070212-10
1: Voltage SIR17Channels EI+
Dioxins isomers (PCDDs)
100
~1314
16.74 1822
305.8987
• ",n
1652'11
&
1.07e8
o
I
I
I~
I
j
,
)~joo
j
28'00 )
~
30'00
i
j
I
Time
14.00
1 6.00
~0.v
20.00
22.00
26.00
32.00
34.00
36.00
-,
Acknowledgement:
Dr.Paul H.Peterman,U.S.Geological Survey,
ColumbiaEnvironmental Research Center,4200New Haven Road - Columbia- Missouri - 6520I U.SA
HROIIII""' .J'#"I«::
+61(0)397622034 AustralianDistributors
Importers
&
Manufacurers
____
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~
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