Dioxins (TCDDs)and furans (TCDFs) in flyashonanRxi®-5SilMScolumn.
95
GCCOLUMNS |
APPLICATION-SPECIFICCOLUMNS
Environmental
also
available
OtherDimensions!
See
page42
forour complete listingof
Rxi®-5SilMScolumns.
Dioxin&FuranCongenersAnalysis
similar
phases
DB-5MS,VF-5ms, CP-Sil 8Low-Bleed/MS
Rxi®-5SilMSColumns
(fusedsilica)
(lowpolarityCrossbond® silarylenephase; selectivity close to5%phenyl/95%dimethyl
arylenepolysiloxane)
• Engineered tobe a lowbleedGC/MS column.
• Excellent inertness for active compounds.
• General purpose columns—ideal forGC/MS analysis of polycyclic aromatic
compounds, chlorinatedhydrocarbons, phthalates, phenols, amines,
organochlorine pesticides, organophosphorus pesticides, drugs, solvent impurities,
andhydrocarbons.
• Temperature range: -60 °C to350 °C.
The Rxi®-5Sil MS stationary phase incorporates phenyl groups in the polymer back-
bone.This improves thermal stability, reduces bleed, andmakes thephase less prone to
oxidation. Rxi®-5Sil MS columns are ideal for GC/MS applications requiring high
sensitivity, includinguse in ion trap systems.
Si
CH
3
CH
3
CH
3
CH
3
Si
O
O
CH
3
CH
3
Si
Rxi®-5SilMSStructure
x
y
Column
Rxi
®
-5Sil MS , 60m, 0.18mm ID, 0.10µm
(cat.# 43607)
Sample
fly ash extract
Diluent:
nonane
Injection
Inj. Vol.:
1µL splitless
Liner:
2mm Splitless liner (cat.# 20712)
Oven
OvenTemp:
120 °C (hold 1min.) to 160 °C at 10 °C/min. to
300 °C at 2.5 °C/min.
Carrier Gas
He, constant flow
FlowRate:
1mL/min.
Detector
Waters AutoSpec UltimaMass Spectrometer
SourceTemp.:
280 °C
IonizationMode: EI
Notes
Electron Ionization at 40eV
Acknowledgement Chromatogram courtesy of KarenMacPherson,
Li Shen,Terry Kolic, and Eric Reiner at theOntario
Ministry of the Environment
GC_EV1194
1236
1237
1238
1239
2378
1278
1267
1289
TCDDs
GC_EV1195
2346
1249
1279
2347
2348
2378
2367
3467
1269
TCDFs
ID
df
temp. limits
30-Meter
60-Meter*
0.18mm 0.10µm -60 to 320/350°C
43607
0.25mm 0.25µm -60 to 330/350°C
13623
*60m, 0.18mm ID, 0.10µm column (cat.# 43607) intended for dioxin and furan analysis only.
Website :
E-mail :
TelNo : 03 9762 2034 . . . inAUSTRALIA
Mar 2011
