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84

www.restek.com

GC COLUMNS |

APPLICATION-SPECIFIC COLUMNS

Foods, Flavors, & Fragrances

PAHs in Food Analysis

Rxi®-PAH Columns

(fused silica)

(midpolarity proprietary phase)

• Ideal for EFSA PAH4 analysis—separates all priority compounds: benz[a]

anthracene, chrysene, benzo[b]fluoranthene, and benzo[a]pyrene.

• Best resolution of chrysene from interfering PAHs, triphenylene, and

cyclopenta[cd]pyrene.

• Complete separation of benzo [b], [k], [ j], and [a] fluoranthenes.

• 360 °C thermal stability allows analysis of low volatility dibenzo pyrenes.

The Rxi®-PAH GC columns were designed by Restek with a higher phenyl-content

stationary phase that provides unique selectivity to separate important polycyclic

aromatic hydrocarbons (PAH) for food safety that cannot be distinguished by mass

spectrometry. Even difficult priority compounds, such as the European Food Safety

Authority (EFSA) PAH4, are easily separated and accurately quantified—results that

cannot be achieved on typical GC columns. Arylene modification and surface bond-

ing of the stationary phase increase thermal stability and ruggedness so relatively

nonvolatile, higher molecular weight PAHs can be analyzed routinely without inter-

ference from column bleed. Excellent column efficiency means that the column can

be trimmed for maintenance purposes many times without losing critical PAH

separations, including those that are part of environmental methods, as well as food

safety testing. The selectivity and efficiency of the Rxi®-PAH column make it ideal

for EFSA PAH4 analysis; chrysene/triphenylene separation and resolution of all

benzofluoranthenes are easily achieved.

30-Meter

40-Meter

60-Meter

ID

df

temp. limits

cat.#

price

cat.#

price

cat.#

price

0.18 mm 0.07 µm to 360 °C

49316

0.25 mm 0.10 µm to 360 °C

49318

49317

Rxi®-PAH GC Column

Resolve Important Isobaric

Polycyclic Aromatic Hydrocarbons

for Food Safety and Environmental

Methods

lit. cat.#

GNTS1718-UNV

www.restek.com

Download your

free copy from

NIST SRM 2260a PAH Mix on Rxi®-PAH

GC_FF1223

Peaks

1. Naphthalene

2. Biphenyl

3. Acenaphthylene

4. Acenaphthene

5. Fluorene

6. Dibenzothiophene

7. Phenanthrene

8. Anthracene

9. 4H-Cyclopenta[def]phenanthrene

10. Fluoranthene

11. Pyrene

12. Benzo[ghi]fluoranthene

13. Benzo[c]phenanthrene

14. Benz[a]anthracene

15. Cyclopenta[cd]pyrene

16. Triphenylene

17. Chrysene

18. Benzo[b]fluoranthene

19. Benzo[k]fluoranthene

20. Benzo[j]fluoranthene

21. Benzo[a]fluoranthene

22. Benzo[e]pyrene

23. Benzo[a]pyrene

24. Perylene

25. Dibenz[a,j]anthracene

26. Dibenz[a,c]anthracene

27. Indeno[1,2,3-cd]pyrene

28. Dibenz[a,h]anthracene

29. Benzo[b]chrysene

30. Picene

31. Benzo[ghi]perylene

32. Anthanthrene

33. Dibenzo[b,k]fluoranthene

34. Dibenzo[a,e]pyrene

35. Coronene

36. Dibenzo[a,h]pyrene

For conditions,

visit

www.restek.com

and enter GC_FF1223 in

the search.

“The Rxi®-PAH column enabled

us to separate important PAH

derivative isomers, which we were

experiencing trouble with for

months. This column is excellent for

PAH, NPAH, and OPAH separation

and I would recommend anyone

working in this field to try it out.

Thank you Restek!”

Mohammed Salim Alam

Research Fellow

University of Birmingham, UK