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GC COLUMNS | APPLICATION-SPECIFIC COLUMNS
Environmental
Rxi®-5Sil MS Columns (fused silica)
(low-polarity phase; Crossbond® 1,4-bis(dimethylsiloxy)phenylene dimethyl polysiloxane)
• Engineered to be a low-bleed GC-MS column.
• Excellent inertness for active compounds.
• General-purpose columns—ideal for GC-MS analysis of semivolatiles, polycyclic
aromatic compounds, chlorinated hydrocarbons, phthalates, phenols, amines,
organochlorine pesticides, organophosphorus pesticides, drugs, solvent impurities,
and hydrocarbons.
• Temperature range: -60 °C to 350 °C.
Rxi®-5Sil MS Structure
95% 5%
CH3
CH3
Si O O
CH3
CH3
Si
CH3
CH3
Si
similar phases
DB-5ms, DB-5msUI, VF-5ms, ZB-5ms,
ZB-SemiVolatiles, Rtx-5Sil MS
15-Meter 30-Meter 60-Meter
ID df temp. limits cat.# price cat.# price cat.# price
0.25 mm0.10 µm -60 to 320/350 °C 13605 13608
0.25 µm -60 to 320/350 °C 13620 13623 13626
0.50 µm -60 to 320/350 °C 13635 13638
1.00 µm -60 to 320/350 °C 13650 13653 13697
0.32 mm0.25 µm -60 to 320/350 °C 13621 13624
0.50 µm -60 to 320/350 °C 13639
1.00 µm -60 to 320/350 °C 13654
0.53 mm1.50 µm -60 to 320/330 °C 13670
10-Meter 20-Meter 40-Meter 60-Meter
ID df temp. limits cat.# price cat.# price cat.# price cat.# price
0.15 mm0.15 µm -60 to 320/350 °C 43815 43816
2.0 µm -60 to 320/350 °C 43817
0.18 mm0.10 µm -60 to 320/350 °C 43607
0.18 µm -60 to 320/350 °C 43602 43605
0.36 µm -60 to 320/350 °C 43604
Polycyclic Aromatic Hydrocarbons (PAHs) Analysis
Similar to: (5%-phenyl)-methylpolysiloxane
Get the protection without the connection!
Se for Rxi®-5Sil MS columns with
built-in Integra-Guard® guard columns.
Integra-Guard® Built-In Guard Column
Polycyclic Aromatic Hydrocarbons on Rxi®-5Sil MS
GC_EV00970
Column Rxi®-5Sil MS, 30 m, 0.25 mm ID,
0.25 µm (cat.# 13623)
Sample PAH mix, 1 µL of 0.005 µg/mL
(IS 2 µg/mL)
SV Calibration mix #5 / 610 PAH Mix
(cat.# 31011)
1-Methylnaphthalene (cat.# 31283)
2-Methylnaphthalene (cat.# 31285)
2-Fluorobiphenyl (cat.# 31091)
Conc.: 5 pg on-column
Injection
Inj. Vol.: 1.0 µL pulsed splitless
(hold 0.15 min)
Liner: Drilled Uniliner® (hole near top)
w/wool (cat.# 21055-200.5)
Inj. Temp.: 300 °C
Pulse Pressure: 20 psi (137.9 kPa)
Pulse Time: 0.2 min
Purge Flow: 60 mL/min
Oven
Oven Temp.: 50 °C (hold 0.5 min) to 290 °C
at 25 °C/min to 320 °C at 5 °C/min
Carrier Gas He, constant flow
Flow Rate: 1.4 mL/min
Detector MS
Mode: SIM
SIM Program: Start Time
Group (min) Ion(s) Dwell (ms)
1 128 m/z 100
2 142 m/z 100
3 172 m/z 100
4 152 m/z 100
5 166 m/z 100
6 178 m/z 100
7 202,244 m/z 100
8 228 m/z 100
9 252,264 m/z 100
10 276,278 m/z 100
Transfer Line
Temp.: 290 °C
Ionization Mode: EI
Peaks tR (min)
1. Naphthalene 4.93
2. 2-Methylnaphthalene 5.58
3. 1-Methylnaphthalene 5.68
4. 2-Fluorobiphenyl (SS) 5.93
5. Acenaphthylene 6.45
6. Acenaphthene 6.62
7. Fluorene 7.12
8. Phenanthrene 8.06
9. Anthracene 8.11
10. Fluoranthene 9.23
11. Pyrene 9.45
12. p-Terphenyl-d14 (IS) 9.61
13. Benzo[a]anthracene 10.65
14. Chrysene 10.69
15. Benzo[b]fluoranthene 11.96
16. Benzo[k]fluoranthene 12.00
17. Benzo[a]pyrene 12.42
18. Perylene-d12 (IS) 12.51
19. Indeno[1,2,3-cd]pyrene 14.19
20. Dibenzo[a,h]anthracene 14.23
21. Benzo[ghi]perylene 14.65
Outstanding response
at 5 pg on-column!