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1,3-Butadiene on Rt®-Alumina BOND/MAPD (Purity Analysis)
GC COLUMNS | PLOT COLUMNS
Fused Silica Alumina BOND Columns
Time (min)
0 2 4 6 8 10 12 14 16 18
11
10
9
8
7
6 5
4
2
1
12
3
6
3
12
12
GC_PC1211
Column Rt®-Alumina BOND/MAPD,
50 m, 0.53 mm ID, 10.0 µm
(cat.# 19778)
Sample Crude 1,3-butadiene
Injection
Inj. Vol.: 10 µL split
Liner: 2.0 mm ID straight inlet liner
(cat.# 20712)
Inj. Temp.: 200 °C
Split Vent
Flow Rate: 100 mL/min
Oven
Oven Temp.: 70 °C (hold 5 min) to 200 °C
at 10 °C/min (hold 0 min)
Carrier Gas He, constant pressure (20
psi, 137.9 kPa)
Detector FID@ 250 °C
Make-up Gas
Flow Rate: 30 mL/min
Make-up Gas
Type: N 2
Data Rate: 20 Hz
Instrument HP5890 GC
Peaks
1. Isobutane
2. n-Butane
3. Propadiene
4. trans-2-Butene
5. 1-Butene
6. Isobutene
7. cis-2-Butene
8. Isopentane
9. n-Pentane
10. 1,2-Butadiene
11. 1,3-Butadiene
12. Methyl acetylene
Rt®-Alumina BOND/MAPD PLOT
columns are made specifically for
the analysis of petrochemicals
and downstream products such
as ethylene, propylene, butylenes,
and butadiene.
free literature
Analyze Trace Polar
Hydrocarbons More
Accurately and Reliably With
New Alumina BOND/MAPD
PLOT Columns
Download your
free copy from
lit. cat.#
PCBR1412A-UNV
Rt®-Alumina BOND/MAPD Columns (fused silica PLOT)
• Optimized deactivation produces maximum response when analyzing trace levels
of acetylene, methyl acetylene, and propadiene.
• Stable response factors make this column ideal for process-type applications where
recalibration must be minimized.
• High loadability reduces peak tailing and improves separations.
• Extended temperature range up to 250 °C for fast elution of high molecular weight
(HMW) hydrocarbons and accelerated column regeneration following exposure to
water.
• Stable to 250 °C.
Restek’s R&D chemists have optimized the deactivation technology applied to our
Rt®-Alumina BOND/MAPD column for improved analysis of trace concentrations of
polar hydrocarbons like acetylene, methyl acetylene, and propadiene in hydrocarbon
streams containing higher levels of C1-C5 hydrocarbons. Our alumina PLOT deac-
tivation produces an incredibly inert column that offers superior reproducibility and
stable response factors to maximize the number of analyses before recalibration is re-
quired. Its high sample capacity reduces peak tailing, thereby improving the separation
of target compounds. In addition, a 250 °C maximum operating temperature lets you
more quickly elute hydrocarbons up to dodecane and reduces regeneration time when
the column is exposed to water from samples or carrier gases.
similar phases
Select Al2O3 MAPD
30-Meter 50-Meter
ID df temp. limits cat.# price cat.# price
0.25 mm 4 µm to 250 °C 19781 —
0.32 mm 5 µm to 250 °C 19779 19780
0.53 mm 10 µm to 250 °C 19777 19778