556
GCCHROMATOGRAMS |
ENVIRONMENTAL
Semivolatiles
Peak List
RetentionTime
1. naphthalene
4.93
2. 2-methylnaphthalene
5.58
3. 1-methylnaphthalene
5.68
4. 2-fluorobiphenyl (SS)
5.93
5. acenaphthylene
6.45
6. acenaphthene
6.62
7. fluorene
7.12
8. phenanthrene
8.06
9. anthracene
8.11
10. fluoranthene
9.23
11. pyrene
9.45
12.
p
-terphenyl-d14 (IS)
9.61
13. benzo(a)anthracene
10.65
14. chrysene
10.69
15. benzo(b)fluoranthene
11.96
16. benzo(k)fluoranthene
12.00
17. benzo(a)pyrene
12.42
18. perylene-d12 (IS)
12.51
19. indeno(1,2,3-cd)pyrene
14.19
20. dibenzo(a,h)anthracene
14.23
21. benzo(ghi)perylene
14.65
Column:
Rxi
®
-5Sil MS, 30m, 0.25mm ID, 0.25µm (cat.# 13623)
Sample:
PAHmix, 1µL of 0.005µg/mL (IS 2µg/mL)
SV CalibrationMix#5 (cat.# 31011)
1-methylnaphthalene (cat.# 31283)
2-methylnaphthalene (cat.# 31285)
2-fluorobiphenyl (cat.# 31091)
Inj.:
1.0µL (5pg on-column concentration),
4mmDrilledUniliner
®
(hole near top) inlet liner w/wool (cat.# 21055-200.5),
pulsed splitless: pulse 20psi@ 0.2min., 60mL/min.@ 0.15min.
Inj. temp.:
300°C
Carrier gas:
helium, constant flow
Flow rate:
1.4mL/min.
Oven temp.:
50°C (hold 0.5min.) to 290°C@ 25°C/min. to 320°C@ 5°C/min.
Det.:
MS
Transfer line
temp:
290°C
Ionization:
EI
Mode:
SIM
Single IonMonitoring Program
Group Time Ion(s)
Dwell (ms)
1
4.00
128
100
2
5.25
142
100
3
5.80
172
100
4
6.25
152
100
5
6.90
166
100
6
7.60
178
100
7
8.75 202, 244
100
8
10.2
228
100
9
11.5 252, 264
100
10
13.5 276, 278
100
PolycyclicAromaticHydrocarbons
Rxi®-5SilMS
GC_EV00970
Full Scale
Outstanding responseat
5pgon-column!
Rxi®Technology!
Exceptionally inert,
ultra low- bleed
capillary columns.
free
literature
AccuratelyQuantifyPAHsDown to5pgOn-Column:GC/MSSimAnalysiswith theNewRxi®-5SilMSColumn
Polycyclicaromatichydrocarbons (PAHs) arecommonenvironmental pollutants, affectingair,water, and soil quality.
Althoughnaturallyoccurring, human impacthas createda steady increase inenvironmental levelsof PAHsand their
byproducts. PAHsare typically formed through the incompletecombustionof organicmaterials, suchaswood, coal,
andoil, but arealsoused inmanufacturingof somemedicines, plastics, andpesticides.ManyPAHsareknownor
suspectedcarcinogens. TheUnitedStatesEnvironmental ProtectionAgencycurrently listsandmandates testingof
the16PAHs theydeemmosthazardous.
Downloadyour freecopy from
ApplicationsNote
lit.cat.#EVAN1284
Website :
E-mail :
TelNo : 03 9762 2034 . . . inAUSTRALIA
Mar 2011
