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138

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GC COLUMNS |

PACKED/MICROPACKED COLUMNS

Application-Specific Packed/Micropacked Columns

D3606 Application Column Set (2 column set)

• Complete resolution of benzene from ethanol—no compromising coelutions.

• Accurate quantification of benzene and toluene.

• Fully conditioned two column set—ready to use out of the box.

• Listed in the appendix of ASTM Method D3606 as an acceptable alternative to

TCEP columns—get better separation of benzene and ethanol while still following

ASTM method requirements.

Conforms to the specifications established in the current ASTMmethod D3606 for the

quantitation of benzene and toluene in spark ignition fuel containing ethanol.

*Please add column instrument configuration suffix number to cat.# when ordering. See chart on

page 141

.

**The column set is designed to accommodate both valve injection and/or syringe injection. Column 1 is configured with

a 2" inlet void to facilitate on-column injection. The inlet is identified on both column 1 and column 2. Note: The inlet of

column 2 is identified for proper orientation for connection to the valve.

Description

cat.#*

price

D3606 Application Column (2 column set)**

Column 1: 6' (1.8 m),

1

/

8

" OD, 2.0 mm ID, nonpolar Rtx-1

Column 2: 16' (4.9 m),

1

/

8

" OD, 2.0 mm ID, proprietary packing material

83606-

Aromatics Analysis

free literature

Resolve Benzene and Toluene

in Spark Ignition Fuels

Containing Ethanol

Download your .

free copy from

lit. cat.# .

PCTS1408-UNV

www.restek.com

Gasoline Containing Ethanol on D3606 Application Column Set by ASTM D3606-10 (Modified)

0

2

4

1

2

3

4

6

8

10

Time (min)

GC_PC1224

Column

D3606 application column (2 column set). Column 1: 6' (1.8 m),

1

/

8

" OD, 2.0 mm ID, nonpolar Rtx®-1;

Column 2: 16' (4.9 m),

1

/

8

" OD, 2.0 mm ID, proprietary packing material (cat.# 83606-800)

Sample

Ethanol-containing gasoline with internal standard (IS)

Diluent:

Injection

Sample valve

Sample Loop Vol.: 1.5 µL

Valve Temp.:

150 °C

Oven

Oven Temp.:

135 °C (hold 12 min)

Carrier Gas

He, constant flow

Flow Rate:

20.0 mL/min

Detector

TCD@ 200 °C

Notes

2.38 minute backflush (must be determined for each GC system).

Peaks

1. Ethanol

2. Benzene

3. 2-Butanol (IS)

4. Toluene

Excellent separation of

ethanol and benzene.

Cut time = 2.38 minutes