Table of Contents Table of Contents
Previous Page  105 / 629 Next Page
Information
Show Menu
Previous Page 105 / 629 Next Page
Page Background www.restek.com

103

GC COLUMNS |

APPLICATION-SPECIFIC COLUMNS

Specially Deactivated

Rt®-

γ

DEXsa Columns

(fused silica)

(2,3-di-acetoxy-6-O-

tert

-butyl dimethylsilyl gamma cyclodextrin added

into 14% cyanopropylphenyl/86% dimethyl polysiloxane)

Uses: Larger organic molecules. Also useful for flavor compounds in fruit juices.

Cyclodextrin Columns for Analyzing Many Chiral Compounds

By adding

β

or

γ

cyclodextrin to our bonded Rtx®-1701 stationary phase, we greatly enhance overall utility and column lifetime for

our chiral columns, compared to columns that have pure cyclodextrin stationary phases. Separations of more than one hundred

chiral compounds have been achieved using our unique DEX columns, and our columns continue to demonstrate stability after

hundreds of temperature program cycles.

Rt®-

β

DEXm Columns

(fused silica)

(permethylated beta cyclodextrin added into 14% cyanopropylphenyl/

86% dimethyl polysiloxane)

Uses: General-purpose chiral phase with many published applications.

Rt®-

β

DEXsm Columns

(fused silica)

(2,3-di-O-methyl-6-O-

tert

-butyl dimethylsilyl beta cyclodextrin added

into 14% cyanopropylphenyl/86% dimethyl polysiloxane)

Uses: Excellent column for most chiral compounds in essential oils.

Rt®-

β

DEXse Columns

(fused silica)

(2,3-di-O-ethyl-6-O-

tert

-butyl dimethylsilyl beta cyclodextrin added into

14% cyanopropylphenyl/86% dimethyl polysiloxane)

Uses: Similar in performance to Rt-

β

DEXsm but provides better resolution for limonene,

linalool, linalyl acetate, ethyl-2-methylbutyrate, 2,3-butane diol, and styrene oxides.

Rt®-

β

DEXsp Columns

(fused silica)

(2,3-di-O-propyl-6-O-

tert

-butyl dimethylsilyl beta cyclodextrin added

into 14% cyanopropylphenyl/86% dimethyl polysiloxane)

Uses: Often useful in dual-column configurations, with the Rt-

β

DEXsm column, for

complex enantiomeric separations.

Rt®-

β

DEXsa Columns

(fused silica)

(2,3-di-acetoxy-6-O-

tert

-butyl dimethylsilyl beta cyclodextrin added into

14% cyanopropylphenyl/86% dimethyl polysiloxane)

Uses: Unique selectivity for esters, lactones, and other fruit flavor components.

Rt®-

β

DEXcst Columns

(fused silica)

(Proprietary cyclodextrin material added into 14% cyanopropylphenyl/

86% dimethyl polysiloxane)

Uses: Proprietary stationary phase, developed specifically for the fragrance industry. Also

used for pharmaceutical applications.

Chiral Analysis

Lower elution temperatures significantly

improve chiral selectivity.

This can be achieved the following ways:

• Faster linear velocities (80 cm/sec) with

hydrogen carrier gas.

• Slower temperature ramp rates (1–2 °C/min).

• Appropriate minimum operating

temperature (40 or 60 °C).

• On-column concentrations of 50 ng or less.

tech tip

Download your free copies from

Grape Flavor Analysis,

Using an Rt®-γDEXsa

GC Column

lit. cat.#

59553

free literature

GC Analysis of Chiral Flavor

Compounds in Apple Juices,

Using Rt®-βDEXsm and

Rt®-βDEXse

Columns

lit. cat.#

59546

www.restek.com

30-Meter

ID

df

temp. limits

cat.#

price

0.25 mm 0.25 µm 40 to 230 °C

13113

0.32 mm

0.25 µm 40 to 230 °C

13112

30-Meter

ID

df

temp. limits

cat.#

price

0.25 mm 0.25 µm 40 to 230 °C

13100

0.32 mm

0.25 µm 40 to 230 °C

13101

30-Meter

ID

df

temp. limits

cat.#

price

0.25 mm 0.25 µm 40 to 230 °C

13105

0.32 mm

0.25 µm 40 to 230 °C

13104

30-Meter

ID

df

temp. limits

cat.#

price

0.25 mm 0.25 µm 40 to 230 °C

13107

0.32 mm

0.25 µm 40 to 230 °C

13106

30-Meter

ID

df

temp. limits

cat.#

price

0.25 mm 0.25 µm 40 to 230 °C

13111

0.32 mm

0.25 µm 40 to 230 °C

13110

30-Meter

ID

df

temp. limits

cat.#

price

0.25 mm 0.25 µm 40 to 230 °C

13109

0.32 mm

0.25 µm 40 to 230 °C

13108

30-Meter

ID

df

temp. limits

cat.#

price

0.25 mm 0.25 µm 40 to 230 °C

13103

0.32 mm

0.25 µm 40 to 230 °C

13102