TheoryofAPI Electrospray
Rayleigh
Limit
Reached
CoulombExplosions
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+
+
-
-
-
-
-
+ +
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+ +
+
--
-
-
-
+
+
+
+
++ - -
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++ - -
Evaporation
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ChargedDroplets
Analyte Ion
Solvent IonCluster
Analyte Ions
Solvent IonClusters
Salts/Ionpairs
Neutrals
Courtesy of Agilent Technologies
